Thioindigo photoswitches available for the modulation of hydrogels’ stiffness by visible light

Authors

  • Fulai Zhao School of Materials Science and Engineering, Tianjin University, Tianjin 300072, People’s Republic of China
Ariticle ID: 101
87 Views, 47 PDF Downloads

DOI:

https://doi.org/10.18686/cest.v1i2.101

Abstract

Chromophore molecules that undergo reversible isomerization under excitation by two different wavelengths of light are commonly referred to as photoswitchable molecules. Through the use of light-induced reversible changes combined with precisely spatial and temporal light control, photoswitchable molecules can be applied in areas such as actuators, optics, molecular motors, and photobiology.

References

Dong L, Feng Y, Wang L, et al. Azobenzene-based solar thermal fuels: Design, properties, and applications. Chemical Society Reviews 2018; 47(19): 7339–7368. doi: 10.1039/c8cs00470f

Fu L, Yang J, Dong L, et al. Solar thermal storage and room-temperature fast release using a uniform flexible azobenzene-grafted polynorborene film enhanced by stretching. Macromolecules 2019; 52(11): 4222–4231. doi: 10.1021/acs.macromol.9b00384

Walden SL, Nguyen PHD, Li HK, et al. Visible light-induced switching of soft matter materials properties based on thioindigo photoswitches. Nature Communications 2023; 14(1). doi: 10.1038/s41467-023-44128-8

Höglsperger F, Vos BE, Hofemeier AD, et al. Rapid and reversible optical switching of cell membrane area by an amphiphilic azobenzene. Nature Communications 2023; 14(1). doi: 10.1038/s41467-023-39032-0

Volarić J, Szymanski W, Simeth NA, et al. Molecular photoswitches in aqueous environments. Chemical Society Reviews 2021, 50(22): 12377–12449. doi: 10.1039/d0cs00547a

Wyman GM. The cis-trans isomerization of conjugated compounds. Chemical Reviews 1955; 55(4): 625–657. doi: 10.1021/cr50004a001

Dittmann M, Graupner FF, Maerz B, et al. Photostability of 4,4′‐dihydroxythioindigo, a mimetic of indigo. Angewandte Chemie International Edition 2013; 53(2): 591–594. doi: 10.1002/anie.201307016

Tong F, Zhou Y, Xu Y, et al. Supramolecular nanomedicines based on host–guest interactions of cyclodextrins. Exploration 2023; 3(4). doi: 10.1002/exp.20210111

Yang W, Zhang W, Chen J, et al. Mono-functionalized pillar[n]arenes: Syntheses, host–guest properties and applications. Chinese Chemical Letters 2024; 35(1): 108740. doi: 10.1016/j.cclet.2023.108740

Liu L, Xiong M, Rong Q, et al. Nucleic acid sensors in vivo: Challenges and opportunities. VIEW 2023; 4(3). doi: 10.1002/viw.20220064

Auma Omondi E, Aluda Kegode A. Chemical pretreatment in lignocellulosic biomass, anaerobic digestion, and biomethanation. Clean Energy Science and Technology 2023; 1(2). doi: 10.18686/cest.v1i2.70

Photoisomerization of a polymerizable thioindigo  linker.

Downloads

Published

2023-12-31

How to Cite

Zhao, F. (2023). Thioindigo photoswitches available for the modulation of hydrogels’ stiffness by visible light. Clean Energy Science and Technology, 1(2), 101. https://doi.org/10.18686/cest.v1i2.101

Issue

Section

Commentary