超临界水热燃烧:基本原理、特性规律及其在能源环境领域中应用与开发

作者

  • 李紫成 热流科学与工程教育部重点实验室,能源与动力工程学院,西安交通大学
  • 李艳辉 热流科学与工程教育部重点实验室,能源与动力工程学院,西安交通大学
  • 王树众 热流科学与工程教育部重点实验室,能源与动力工程学院,西安交通大学
  • 任萌萌 冶金工程学院,西安建筑科技大学
  • 段远望 热流科学与工程教育部重点实验室,能源与动力工程学院,西安交通大学
  • 刘慧 热流科学与工程教育部重点实验室,能源与动力工程学院,西安交通大学
Ariticle ID: 93
92 Views, 14 PDF Downloads

DOI:

https://doi.org/10.18686/cncest.v1i2.93

关键词:

超临界水热燃烧;燃烧特性;数值模拟;废物处理;煤炭地下气化;稠油热采

摘要

超临界水热燃烧技术是一种“水火相容”、无NOx与SOx生成的新型清洁均相燃烧技术,有望推动有机废物高效处理、传统化石能源清洁利用、稠油高效热采等领域技术的变革性发展。本文在归纳近年来超临界水热燃烧技术基本特点的基础上,重点从实验研究、数值计算两个角度总结分析了典型燃料的超临界水热燃烧特性与规律,以及在能源环境领域变革性工程应用与开发的最新进展。指出降低着火温度与熄火温度是推进超临界水热燃烧技术应用的关键,考虑真实流体效应与湍流-反应交互作用才能正确反映燃烧过程。此外,超临界水热燃烧作为体系热量与反应介质供给来源,可实现高浓有机废物高效去除、煤炭清洁燃烧与原位制氢以及生成多元热流体强化稠油热采。当前,超临界水热燃烧强迫点火技术、反应器设计准则、关键设备防腐仍是未来研究的重点,对推进超临界水热燃烧技术工程化成熟具有重要意义。

参考

National Bureau of Statistics. Statistical bulletin of the national economic and social development of the People’s

Republic of China in 2022 (Chinese). China Statistics 2023; 3: 12–29.

Liu S, Chang Z, Liu J. Key technologies and prospect for in-situ gasification mining of deep coal resources.

Journal of Mining Science and Technology 2021; 6(3): 261–270. doi: 10.19606/j.cnki.jmst.2021.03.002

Huang S, Cao M, Cheng L. Experimental study on the mechanism of enhanced oil recovery by multi-thermal fluid

in offshore heavy oil. International Journal of Heat and Mass Transfer 2018; 122: 1074–1084. doi:

1016/j.ijheatmasstransfer.2018.02.049

Schilling W, Franck EU. Combustion and diffusion flames at high pressures to 2000 bar. Berichte der

Bunsengesellschaft für physikalische Chemie 1988; 92(5): 631–636. doi: 10.1002/bbpc.198800149

Steeper RR, Rice SF, Brown MS, et al. Methane and methanol diffusion flames in supercritical water. The Journal

of Supercritical Fluids 1992; 5(4): 262–268. doi: 10.1016/0896-8446(92)90017-e

Sobhy A, Guthrie RIL, Butler IS, et al. Naphthalene combustion in supercritical water flames. Proceedings of the

Combustion Institute 2009; 32(2): 3231–3238. doi: 10.1016/j.proci.2008.06.173

Meier T, Schuler MJ, Stathopoulos P, et al. Hot surface ignition and monitoring of an internal oxygen–ethanol

hydrothermal flame at 260 bar. The Journal of Supercritical Fluids 2017; 130: 230–238. doi:

1016/j.supflu.2016.09.015

Wellig B, Weber M, Lieball K, et al. Hydrothermal methanol diffusion flame as internal heat source in a SCWO

reactor. The Journal of Supercritical Fluids 2009; 49(1): 59–70. doi: 10.1016/j.supflu.2008.11.021

Stathopoulos P, Ninck K, von Rohr PR. Hot-wire ignition of ethanol–oxygen hydrothermal flames. Combustion

and Flame 2013; 160(11): 2386–2395. doi: 10.1016/j.combustflame.2013.05.006

Bermejo MD, Cabeza P, Queiroz JPS, et al. Analysis of the scale up of a transpiring wall reactor with a

hydrothermal flame as a heat source for the supercritical water oxidation. The Journal of Supercritical Fluids

; 56(1): 21–32. doi: 10.1016/j.supflu.2010.11.014

Bermejo MD, Jiménez C, Cabeza P, et al. Experimental study of hydrothermal flames formation using a tubular

injector in a refrigerated reaction chamber. Influence of the operational and geometrical parameters. The Journal

of Supercritical Fluids 2011; 59: 140–148. doi: 10.1016/j.supflu.2011.08.009

Cabeza P, Silva Queiroz JP, Criado M, et al. Supercritical water oxidation for energy production by hydrothermal

flame as internal heat source. Experimental results and energetic study. Energy 2015; 90: 1584–1594. doi:

1016/j.energy.2015.06.118

Hicks MC, Hegde UG, Kojima JJ. Hydrothermal ethanol flames in Co-flow jets. The Journal of Supercritical

Fluids 2019; 145: 192–200. doi: 10.1016/j.supflu.2018.12.010

Xu D, Wang S, Huang C, et al. Transpiring wall reactor in supercritical water oxidation. Chemical Engineering

Research and Design 2014; 92(11): 2626–2639. doi: 10.1016/j.cherd.2014.02.028

Cui C, Li Y, Wang S, et al. Review on an advanced combustion technology: Supercritical hydrothermal

combustion. Applied Sciences 2020; 10(5): 1645. doi: 10.3390/app10051645

清洁能源科学与技术 第 1 卷 第 2 期(2023) 25/28

Shaw RW. Supercritical water a medium for chemistry. Chemical Engineering News 1991; 69(51): 26–39. doi:

1021/cen-v069n051.p026

Huang G. Properties of water in supercritical state (Chinese). Northwest China Electric Power 2004; 4: 82–84, 86.

Liu X, Guo Y, Lin L. Application of super (sub)critical water in chemical reactions (Chinese). Inner Mongolia

Petrochemical Industry 2008; 3: 34–37.

Tian Y, Feng J, Qin Y, et al. Properties of supercritical water and its application in chemical reactions (Chinese).

Chemistry (Huaxue Tongbao) 2002; 6: 396–402.

YangK, Xu M, Lin C. Physical and chemical properties of supercritical water (Chinese). Journal of Zhejiang

University of Technology 2001; 4: 66–70.

Zhang L, Chen L, Zhao X, et al. Properties of supercritical water and its application. Chemical Industry and

Engineering 2003; 20(1): 33–38, 54.

Augustine C, Tester JW. Hydrothermal flames: From phenomenological experimental demonstrations to

quantitative understanding. The Journal of Supercritical Fluids 2009; 47(3): 415–430. doi:

1016/j.supflu.2008.10.003

Reddy SN, Nanda S, Hegde UG, et al. Ignition of hydrothermal flames. RSC Advances 2015; 5(46): 36404–36422.

doi: 10.1039/c5ra02705e

Jiang Z, Li Y, Wang S, et al. Review on mechanisms and kinetics for supercritical water oxidation processes.

Applied Sciences 2020; 10(14): 4937. doi: 10.3390/app10144937

Henrikson JT, Grice CR, Savage PE. Effect of water density on methanol oxidation kinetics in supercritical water.

The Journal of Physical Chemistry A 2006; 110(10): 3627–3632. doi: 10.1021/jp057184u

Richard Holgate H, Tester JW. Fundamental kinetics and mechanisms of hydrogen oxidation in supercritical

water. Combustion Science and Technology 1993; 88(5–6): 369–397. doi: 10.1080/00102209308947245

Fujii T, Hayashi R, Kawasaki S, et al. Water density effects on methanol oxidation in supercritical water at high

pressure up to 100 MPa. The Journal of Supercritical Fluids 2011; 58(1): 142–149. doi:

1016/j.supflu.2011.04.004

Boock LT, Klein MT. Lumping strategy for modeling the oxidation of C1–C3 alcohols and acetic acid in hightemperature water. Industrial & Engineering Chemistry Research 1993; 32(11): 2464–2473. doi:

1021/ie00023a004

Cabeza P, Bermejo MD, Jiménez C, et al. Experimental study of the supercritical water oxidation of recalcitrant

compounds under hydrothermal flames using tubular reactors. Water Research 2011; 45(8): 2485–2495. doi:

1016/j.watres.2011.01.029

Zhang J, Wang S, Xu D, et al. Kinetics study on hydrothermal combustion of methanol in supercritical water.

Chemical Engineering Research and Design 2015; 98: 220–230. doi: 10.1016/j.cherd.2015.05.002

Zhang F, Zhang Y, Xu C, et al. Experimental study on the ignition and extinction characteristics of the

hydrothermal flame. Chemical Engineering & Technology 2015; 38(11): 2054–2066. doi: 10.1002/ceat.201300571

Bermejo MD, Cabeza P, Bahr M, et al. Experimental study of hydrothermal flames initiation using different static

mixer configurations. The Journal of Supercritical Fluids 2009; 50(3): 240–249. doi:

1016/j.supflu.2009.06.010

Sobhy A, Butler IS, Kozinski JA. Selected profiles of high-pressure methanol–air flames in supercritical water.

Proceedings of the Combustion Institute 2007; 31(2): 3369–3376. doi: 10.1016/j.proci.2006.07.253

Reddy SN, Nanda S, Kumar P, et al. Impacts of oxidant characteristics on the ignition of n-propanol-air

hydrothermal flames in supercritical water. Combustion and Flame 2019; 203: 46–55. doi:

1016/j.combustflame.2019.02.004

Hirth Th, Franck EU. Oxidation and hydrothermolysis of hydrocarbons in supercritical water at high pressures.

Berichte der Bunsengesellschaft für physikalische Chemie 1993; 97(9): 1091–1097. doi:

1002/bbpc.19930970905

Savage PE. Organic chemical reactions in supercritical water. Chemical Reviews 1999; 99(2): 603–622. doi:

1021/cr9700989

Meier T, Stathopoulos P, von Rohr PR. Hot surface ignition of oxygen–ethanol hydrothermal flames. The Journal

of Supercritical Fluids 2016; 107: 462–468. doi: 10.1016/j.supflu.2014.11.012

Wellig B, Lieball K, von Rohr Rudolf. Operating characteristics of a transpiring-wall SCWO reactor with a

hydrothermal flame as internal heat source. Journal of Supercritical Fluids 2005; 34(1): 35–50. doi:

1016/j.supflu.2004.07.003

Zhang F, Chen S, Xu C, et al. Experimental study on the effects of operating parameters on the performance of a

transpiring-wall supercritical water oxidation reactor. Desalination 2012; 294: 60–66. doi:

1016/j.desal.2012.03.013

Zhang F, Xu C, Zhang Y, et al. Experimental study on the operating characteristics of an inner preheating

transpiring wall reactor for supercritical water oxidation: Temperature profiles and product properties. Energy

; 66: 577–587. doi: 10.1016/j.energy.2014.02.003

清洁能源科学与技术 第 1 卷 第 2 期(2023) 26/28

Bermejo MD, Fdez-Polanco F, Cocero MJ. Experimental study of the operational parameters of a transpiring wall

reactor for supercritical water oxidation. The Journal of Supercritical Fluids 2006; 39(1): 70–79. doi:

1016/j.supflu.2006.02.006

Serikawa R. Hydrothermal flames in supercritical water oxidation: Investigation in a pilot scale continuous

reactor. Fuel 2002; 81(9): 1147–1159. doi: 10.1016/s0016-2361(02)00015-7

Cabeza P, Queiroz JPS, Arca S, et al. Sludge destruction by means of a hydrothermal flame. Optimization of

ammonia destruction conditions. Chemical Engineering Journal 2013; 232: 1–9. doi: 10.1016/j.cej.2013.07.040

Príkopský K. Characterization of Continuous Diffusion Flames in Supercritical Water [PhD thesis]. ETH Zurich;

Schanzenbächer J, Taylor JD, Tester JW. Ethanol oxidation and hydrolysis rates in supercritical water. The

Journal of Supercritical Fluids 2002; 22(2): 139–147. doi: 10.1016/s0896-8446(01)00119-x

Vogel F, Blanchard JLD, Marrone PA, et al. Critical review of kinetic data for the oxidation of methanol in

supercritical water. The Journal of Supercritical Fluids 2005; 34(3): 249–286. doi: 10.1016/j.supflu.2003.12.018

Ren M. Research on Supercritical Hydrothermal Combustion Mechanism Using Reaction Kinetics Coupled Flow

Model [PhD thesis]. Xi’an Jiaotong University; 2019.

Brock EE, Savage PE. Detailed chemical kinetics model for supercritical water oxidation of C1 compounds and

H2. AIChE Journal 1995; 41(8): 1874–1888. doi: 10.1002/aic.690410806

Baulch DL, Cobos CJ, Cox RA, et al. Evaluated kinetic data for combustion modelling. Journal of Physical and

Chemical Reference Data 1992; 21(3): 411. doi: 10.1063/1.555908

Baulch DL, Cobos CJ, Cox RA, et al. Evaluated kinetic data for combustion modeling. Supplement I. Journal of

Physical and Chemical Reference Data 1994; 23(6): 847–848. doi: 10.1063/1.555953

Rice SF, Croiset E. Oxidation of simple alcohols in supercritical water III. Formation of intermediates from

ethanol. Industrial & Engineering Chemistry Research 2000; 40(1): 86–93. doi: 10.1021/ie000372g

Marinov NM. A detailed chemical kinetic model for high temperature ethanol oxidation. International Journal of

Chemical Kinetics 1999; 31(3): 183–220. doi: 10.1002/(SICI)1097-4601(1999)31:3<183::AID-KIN3>3.0.CO;2-X

Ploeger JM, Green WH, Tester JW. Co-oxidation of methylphosphonic acid and ethanol in supercritical water. The

Journal of Supercritical Fluids 2006; 39(2): 239–245. doi: 10.1016/j.supflu.2006.03.003

Ren M, Wang S, Zhang J, et al. Characteristics of methanol hydrothermal combustion: Detailed chemical kinetics

coupled with simple flow modeling study. Industrial & Engineering Chemistry Research 2017; 56(18): 5469–

doi: 10.1021/acs.iecr.7b00886

Li L, Chen P, Gloyna EF. Generalized kinetic model for wet oxidation of organic compounds. AIChE Journal

; 37(11): 1687–1697. doi: 10.1002/aic.690371112

Hayashi R, Onishi M, Sugiyama M, et al. Kinetic analysis on alcohol concentration and mixture effect in

supercritical water oxidation of methanol and ethanol by elementary reaction model. The Journal of Supercritical

Fluids 2007; 40(1): 74–83. doi: 10.1016/j.supflu.2006.04.006

Ploeger JM, Green WH, Tester JW. Co‐oxidation of ammonia and ethanol in supercritical water, part 2: Modeling

demonstrates the importance of H2NNOx. International Journal of Chemical Kinetics 2008; 40(10): 653–662. doi:

1002/kin.20345

Benjamin KM, Savage PE. Detailed chemical kinetic modeling of methylamine in supercritical water. Industrial &

Engineering Chemistry Research 2005; 44(26): 9785–9793. doi: 10.1021/ie050926l

Dinaro JL, Howard JB, Green WH, et al. Analysis of an elementary reaction mechanism for benzene oxidation in

supercritical water. Proceedings of the Combustion Institute 2000; 28(2): 1529–1536. doi: 10.1016/s0082-

(00)80550-0

Gao Z, Wang H, Song C, et al. Real-fluid effects on laminar diffusion and premixed hydrothermal flames. The

Journal of Supercritical Fluids 2019; 153: 104566. doi: 10.1016/j.supflu.2019.104566

Chung TH, Ajlan M, Lee LL, et al. Generalized multiparameter correlation for nonpolar and polar fluid transport

properties. Industrial & Engineering Chemistry Research 1988; 27(4): 671–679. doi: 10.1021/ie00076a024

Narayanan C, Frouzakis C, Boulouchos K, et al. Numerical modelling of a supercritical water oxidation reactor

containing a hydrothermal flame. The Journal of Supercritical Fluids 2008; 46(2): 149–155. doi:

1016/j.supflu.2008.04.005

Sierra-Pallares J, Teresa Parra-Santos M, García-Serna J, et al. Numerical modelling of hydrothermal flames.

Micromixing effects over turbulent reaction rates. The Journal of Supercritical Fluids 2009; 50(2): 146–154. doi:

1016/j.supflu.2009.05.001

Poling BE, Prausnitz JM, O’Connell JP. The Properties of Gases and Liquids, 5th ed. McGraw-Hill; 2001.

Hjertager LK, Hjertager BH, Solberg T. CFD modelling of fast chemical reactions in turbulent liquid flows.

Computers & Chemical Engineering 2002; 26(4–5): 507–515. doi: 10.1016/s0098-1354(01)00799-2

Mathur GP, Thodos G. The self‐diffusivity of substances in the gaseous and liquid states. AIChE Journal 1965;

(4): 613–616. doi: 10.1002/aic.690110411

清洁能源科学与技术 第 1 卷 第 2 期(2023) 27/28

Zhang J, Ren M, Li Y, et al. Continuous supercritical hydrothermal combustion experimental and burner structure

optimization simulation study. Chemical Engineering Research and Design 2022; 188: 69–80. doi:

1016/j.cherd.2022.09.039

Song C. Direct Numerical Simulation Study of Supercritical Hydrothermal Combustion (Chiense) [PhD thesis].

Zhejiang University; 2020.

Qian L, Wang S, Ren M, et al. Co-oxidation effects and mechanisms between sludge and alcohols (methanol,

ethanol and isopropanol) in supercritical water. Chemical Engineering Journal 2019; 366: 223–234. doi:

1016/j.cej.2019.02.046

Ren M, Wang S, Yang C, et al. Supercritical water oxidation of quinoline with moderate preheat temperature and

initial concentration. Fuel 2019; 236: 1408–1414. doi: 10.1016/j.fuel.2018.09.091

Zhang J, Li P, Lu J, et al. Supercritical water oxidation of ammonia with methanol as the auxiliary fuel:

Comparing with isopropanol. Chemical Engineering Research and Design 2019; 147: 160–170. doi:

1016/j.cherd.2019.05.010

Zhang J, Li P, Lu J, et al. Supercritical hydrothermal combustion of nitrogen-containing compounds in a tubular

reactor. Fuel 2020; 275: 117889. doi: 10.1016/j.fuel.2020.117889

Fujie M, Inui A, Anjo KJ, et al. Study of combustion behavior of brown coal in supercritical water. High Pressure

Research 2001; 20(1–6): 385–392. doi: 10.1080/08957950108206186

Ma H. Research on Basic Issues of Coal Supercritical Water Gasification Coupled Hydrothermal Combustion

Power Generation System (Chiense) [PhD thesis]. Xi’an Jiaotong University; 2013.

Bermejo MD, Cocero MJ, Fernández-Polanco F. A process for generating power from the oxidation of coal in

supercritical water. Fuel 2004; 83(2): 195–204. doi: 10.1016/s0016-2361(03)00256-4

Liang W. Research on the Hydrothermal Combustion of Coal in Supercritical Water [Master’s thesis]. Xi’an

Jiaotong University; 2007.

Chen J, Wang L, Cheng Z, et al. Performance simulation and thermodynamics analysis of hydrogen production

based on supercritical water gasification of coal. International Journal of Hydrogen Energy 2021; 46(56): 28474–

doi: 10.1016/j.ijhydene.2021.06.097

Zhang F, Wang S, Duan Y, et al. Thermodynamic assessment of hydrothermal combustion assisted fossil fuel insitu gasification in the context of sustainable development. Fuel 2023; 335: 127053. doi:

1016/j.fuel.2022.127053

Liu W, Wan Y, Xiong Y, et al. Green hydrogen standard in China: Standard and evaluation of low-carbon

hydrogen, clean hydrogen, and renewable hydrogen. International Journal of Hydrogen Energy 2022; 47(58):

–24591. doi: 10.1016/j.ijhydene.2021.10.193

Guo Y. Research progress of viscosity reduction of heavy oil. Contemporary Chemical Industry 2019; 48(1): 4.

He W, Li Z, Li Y, et al. Prospects of supercritical hydrothermal combustion as recovery technology for heavy oil

reservoirs. Geoenergy Science and Engineering 2023; 227: 211795. doi: 10.1016/j.geoen.2023.211795

Wang S, Xu H, Li Y, et al. A Supercritical Hydrothermal Combustion Steam Generator for Ultra-Deep

Underground Heavy Oil Thermal Recovery (Chinese). China Patent 110617466A, 27 December 2019.

Wang S, Cui C, Li Y, et al. A Supercritical Hydrothermal Combustion Device Suitable for High-Viscosity Fuels

(Chinese). China Patent CN110645555A, 3 January 2020.

Geng Y, Wang S, Zhang F, et al. Numerical investigations on hydrothermal flame characteristics of water-cooled

hydrothermal burner. International Journal of Chemical Reactor Engineering 2023; 21(10): 1225–1239. doi:

1515/ijcre-2023-0040

西安交通大学王树众教授团队开发的超临界多元热流体发生器。

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文章引用

李紫成, 李艳辉, 王树众, 任萌萌, 段远望, & 刘慧. (2023). 超临界水热燃烧:基本原理、特性规律及其在能源环境领域中应用与开发. 清洁能源科学与技术, 1(2), 93. https://doi.org/10.18686/cncest.v1i2.93

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