用于电解水制“绿氢”的过渡金属硫族化合物基催化剂设计原理与调控策略
DOI:
https://doi.org/10.18686/cncest357关键词:
电催化裂解水；氢气析出反应；氧气析出反应；过渡金属硫族化合物；电催化性能摘要
发展可再生能源电解水制氢技术是实现氢能经济规模化应用的重要前提。目前，商用的电解水催化剂为铂族贵金属，但其储量稀少、价格高昂，严重限制了电解水制氢的实际应用。作为极具潜力的铂族贵金属替代材料，过渡金属硫族化合物（transition metal dichalcogenides, TMDs）因其本征催化活性高、成本低廉等特点，受到了科研工作者们的广泛关注。然而，TMDs的催化性能与铂族贵金属仍存在一定差距，为此，科研工作者们围绕其性能提升和催化机理开展了许多深入而系统的研究。本文结合电解水基本反应原理、电解水催化剂材料的设计思路以及TMDs的结构与电催化性能，全面总结了提升TMDs材料电解水催化性能的策略和方法。最后，对这一蓬勃发展的领域所面临的挑战和未来的研究方向进行了展望。
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