等离子体技术在氢能源研究中的应用进展
DOI:
https://doi.org/10.18686/cncest312关键词:
等离子体；氢能源；电解水催化剂；甲烷裂解；氨气裂解；合成氨；机器学习摘要
氢能源是实现碳中和目标的可选方案之一。在氢能源生产、运输、使用环节，等离子体技术都起到了一定的辅助作用。尤其是等离子体由可再生的电能激发产生，是产生氢能源的一种绿色可替代技术手段。本综述总结了近年来等离子体技术在氢能源领域的作用，重点介绍了等离子体在电解水制氢、裂解甲烷、裂解氨气和合成氨的作用。等离子体在辅助合成电解水催化剂的作用主要体现在为催化剂基底材料刻蚀微沟槽，制造催化剂空穴，增加原子修饰三个方面。等离子体在裂解甲烷和氨气得到氢气，合成氨三个方面的作用主要是联合催化剂提高工艺指标。鉴于等离子体制备催化剂的重要性，我们建议采用机器学习辅助高通量筛选获得最佳理论性能的催化剂结构之后，再使用等离子体针对性合成催化剂。与此同时，使用第一性原理计算阐释催化剂催化机理。
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