采用磷钨酸与多巴胺化学键合形成的水不溶性杂化物的高性能质子交换膜
DOI:
https://doi.org/10.18686/cncest.v2i2.181关键词:
燃料电池质子交换膜；磺化聚醚醚酮；磷钨酸；聚多巴胺；水热法摘要
杂多酸可以将水保留在质子交换膜中，从而提高其在高温和低湿度条件下的质子电导率；然而，它们在水中的高溶解度会导致浸出，从而限制了它们的进一步应用。在此，我们利用磷钨酸（HPW）和聚多巴胺（PDA）颗粒，通过水热反应制备了不溶于水的PDA/HPW混合物（PDW）。PDW中PDA的氨基与HPW化学键合，成为HPW的锚。含有15wt% PDW的磺化聚醚醚酮（SPEEK）复合膜（SPEEK/PDW-15）在液态水中的质子电导率在25 ℃时为0.052 S cm–1。比SPEEK对照膜（0.032 S cm–1）高出63%。在浸入水中80天的测试中，SPEEK/PDW-15复合膜也显示出稳定的质子电导率。
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