碳和二氧化硅包裹的无定形CuO混合材料的电化学还原CO到液态C2+的高法拉第效率
DOI:
https://doi.org/10.18686/cncest.v2i2.178关键词:
一氧化碳；电还原；C2+产物；铜基催化剂；二氧化硅摘要
一氧化碳（CO）是公认的二氧化碳（CO2）电解还原为C2+产品的关键中间体之一，这也是近期的研究热点。开发一种能实现C-C偶联的高效催化剂对于生产C2+产物非常重要。在本研究中，我们提出了一种简易的方法，即通过静电组装耦合硅阳离子和铜盐，并结合水热法构建碳硅包铜非晶杂化材料，即CuO@C-SiO2-X（X表示催化剂制备温度），作为CO主要还原为液态C2+产物的高效电催化剂。CuO@C-SiO2-X催化剂表现出优异的电催化活性和选择性，尤其是对C2+液体产物的选择性，其法拉第效率（FE）最高达81.5%。此外，催化剂还具有良好的稳定性。碳的存在增强了电子传导性，SiO2可以阻止无定形的CuO聚集成晶体结构。本研究不仅为CO电催化还原为液态C2+化学品提供了一种高效催化剂，还为在CO还原过程中构建对C2+产物具有高选择性的铜基催化剂提供了一种方案。
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